My mother has a PC running WinXp using an Asus P5KPL-AM mobo.
On startup it hangs for quite some time. When/if it does boot up it seems to be running ok. I have noticed that there is usb storage devices (labeled drives D,E,F and G)detected both in windows and the BIOS. There are no USB drives connected and to my knowledge there has never been. The only USB devices that should be installed are a printer and wireless mouse/keyboard. I have removed these to make sure that these are not the cause. I have also attempted to uninstall these extra devices but they just get reinstalled on startup.
Im no expert but everything else looks ok to me and I am wondering if maybe it could be timing out looking for these devices on startup.
Some machine (like Packard Bell), have an internal card reader slot waiting for a connection (up to 4 drives), if you are not using it, I believe it can be unplugged from the motherboard, or you may be able to go into BIOS and disable it from there.
I suggest you backup all working files before you attempt this as a safeguard. Terry
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