I would advise to do a fresh install of Windows, I am assuming that you are using 7.Then before you install your programs, your libraries to another drive and just keep your SSD for OS and programs, everything else put on another drive.
Here's a few tweaks that you also might like to do: SSD tweaks and also from OCZ: OCZ SSD
Many thanks for all the advice, I only want to put the OS Windows 7 and installed Programs onto the new drive, the partition size on my old disk is 92GB and it only has Windows 7 and a few programs on it that total up to 28GB the rest of the partition is empty. So if all goes well I should still have plenty of room to play with on the new drive.
I have moved an OS before, but that was like 20 years ago and not to anything like this SSD, I guess it`s that drive that was worrying me.
Thanks a lot for all your help, it is very much appreciated.