Although you can copy the contents of the program folder to the new system that is all you can do. The program itself will not work because the registry etries are missing. To use the program, you will need the CD again.
NTSC - Its NTFS...
You can transfer files from a FAT32 to an NTFS file system because i have done it.
To find out what file system the new machine is usinf. Right click the C drive and go down to prpperties and then look at "File system".
Its most likely to be NTFS anyway.
Also it will have a USB port.