I am a fully paid subscriber to Sky and want to download Sky Go to my laptop.
Then I would like to upload Sky Go from laptop to a new Samsung Smart TV(Model UE32H4500/4510). Is this possible? Would appreciate your help before I buy the new TV.
I don't think it's possible. What you can do with a Samsung Smart TV - most smart TVs, in fact - is very limited. If it's not available 'out of the box', it usually can't be done. (As an example: few smart TVs support the range of on demand services that the Samsung does, which is one of its main attractions - but you can't just add 4OD, or ITVPlayer, for example, to other TVs if they're not there to start with.)